Microwave‐assisted N‐alkylation of amines with alcohols catalyzed by MnCl2: Anticancer, docking, and DFT studies
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DOI: 10.1002/ardp.202100443
Abstract: A new protocol for the N‐alkylation of amines with alcohols for the synthesis of tertiary amines in the presence of MnCl2 as a catalyst, under microwave conditions, is described. The advantages of this protocol include… read more here.
Keywords: assisted alkylation; microwave assisted; amines alcohols; alkylation amines ... See more keywords
Ru(II)-NHC catalysed N-Alkylation of amines with alcohols under solvent-free conditions
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DOI: 10.1016/j.ica.2021.120294
Abstract: Abstract The reaction of [RuCl2(p-cymene)]2 with in situ prepared Ag-N-heterocyclic carbene (NHC) complexes yields a series of [RuCl2(p-cymene)(NHC)] complexes (2). All of the complexes have been characterised by elemental analysis, and 1H NMR and 13C… read more here.
Keywords: nhc catalysed; alkylation; alkylation amines; catalysed alkylation ... See more keywords
Synthesis of an Fe–Pd bimetallic catalyst for N-alkylation of amines with alcohols via a hydrogen auto-transfer methodology
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DOI: 10.1039/d0gc03725g
Abstract: A bimetallic catalyst, Fe10Pd1/NC500, was prepared, and it efficiently catalyzed the N-alkylation of amines with alcohols due to the synergistic effects inside. read more here.
Keywords: amines alcohols; methodology; alkylation amines; bimetallic catalyst ... See more keywords
Iridium/graphene nanostructured catalyst for the N-alkylation of amines to synthesize nitrogen-containing derivatives and heterocyclic compounds in a green process
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DOI: 10.1039/d1ra09052f
Abstract: A facile iridium/graphene-catalyzed methodology providing an efficient synthetic route for C–N bond formation is reported. This catalyst can directly promote the formation of C–N bonds, without pre-activation steps, and without solvents, alkalis and other additives.… read more here.
Keywords: alkylation amines; process; iridium graphene; graphene nanostructured ... See more keywords
Reusable Co-nanoparticles for general and selective N-alkylation of amines and ammonia with alcohols
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DOI: 10.1039/d1sc05913k
Abstract: A general cobalt-catalyzed N-alkylation of amines with alcohols by borrowing hydrogen methodology to prepare different kinds of amines is reported. The optimal catalyst for this transformation is prepared by pyrolysis of a specific templated material,… read more here.
Keywords: general selective; alkylation amines; amines ammonia; reusable nanoparticles ... See more keywords
Alkylation of amines with allylic alcohols and deep eutectic solvents as metal-free and green promoters
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DOI: 10.1039/d3gc01017a
Abstract: A novel approach for the allylic alkylation of anilines, hydrazides, indole derivatives and additional interesting nucleophiles is described, which involves the direct use of a variety of allylic alcohols under... read more here.
Keywords: alcohols deep; deep eutectic; amines allylic; allylic alcohols ... See more keywords