Tungsten-Catalyzed Direct N-Alkylation of Anilines with Alcohols.
Sign Up to like & getrecommendations! Published in 2020 at "ChemSusChem"
DOI: 10.1002/cssc.202002830
Abstract: The implementation of non-noble metals mediated chemistry is a major goal in homogeneous catalysis. Borrowing hydrogen/hydrogen autotransfer (BH/HA) reaction, as a straightforward and sustainable synthetic method, has attracted considerable attention in the development of non-noble… read more here.
Keywords: alkylation anilines; catalyzed direct; alkylation; anilines alcohols ... See more keywords
Ruthenium-catalysed N-alkylation of anilines with primary carbohydrate alcohols via borrowing hydrogen strategy.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01931d
Abstract: Ruthenium-catalysed N-alkylation of anilines with sugar derivatives proceeded via the borrowing hydrogen strategy. Primary carbohydrate alcohols were successfully applied to N-alkylation of aniline derivatives to give the corresponding aminosugars in high yields. read more here.
Keywords: via borrowing; alkylation anilines; alkylation; borrowing hydrogen ... See more keywords
HFIP-promoted para-selective alkylation of anilines and phenols with tertiary alkyl bromides
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DOI: 10.1039/d3qo00342f
Abstract: A Hexafluoroisopropanol-promoted highly regioselective Friedel-Crafts alkylation of arenes has been developed in this study. Various arenes, including anilides, anisoles, and phenols, were compatible with the reaction, leading to the para-alkylated... read more here.
Keywords: alkylation anilines; para selective; alkylation; hfip promoted ... See more keywords