General and Anti‐Markovnikov Selective Ni‐Catalyzed Alkylation of Arenes and Heteroarenes with Non‐Activated Olefins
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DOI: 10.1002/ejoc.202500590
Abstract: The majority of C–C coupling reactions between arenes and olefins result in the formation of branched isomer products, exhibiting what is known as Markovnikov selectivity. However, alternative catalytic strategies are required to modulate this selectivity,… read more here.
Keywords: general anti; anti markovnikov; markovnikov selective; selective catalyzed ... See more keywords
Regioselective Radical Alkylation of Arenes Using Evolved Photoenzymes.
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DOI: 10.1021/jacs.3c03607
Abstract: Substituted arenes are ubiquitous in molecules with medicinal functions, making their synthesis a critical consideration when designing synthetic routes. Regioselective C-H functionalization reactions are attractive for preparing alkylated arenes; however, the selectivity of existing methods… read more here.
Keywords: alkylation arenes; arenes using; alkylation; radical alkylation ... See more keywords