Scandium-Catalyzed para-Selective Alkylation of Aromatic Amines with Alkenes.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b03451
Abstract: An efficient para-alkylation of primary and secondary anilines with a variety of sterically encumbered alkenes using a simple β-diketiminato scandium catalyst is reported. This protocol features 100% atom economy, excellent chemo- and regioselectivity, broad substrate… read more here.
Keywords: scandium catalyzed; selective alkylation; para selective; alkylation aromatic ... See more keywords
A binuclear Cu(II) complex as an efficient photocatalyst for N-alkylation of aromatic amines.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01771g
Abstract: Visible-light driven photoreactions using transition metal complexes as catalysts are currently a research hotspot in developing environmentally friendly sustainable processes. To develop a potential copper-based photocatalyst, a binuclear Cu(II) complex has been synthesized using a… read more here.
Keywords: photocatalyst alkylation; alkylation aromatic; photocatalyst; complex efficient ... See more keywords