Iridium-Catalyzed C-Alkylation of Methyl Group on N-Heteroaromatic Compounds using Alcohols.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c02635
Abstract: In this study, we developed a catalytic system for the C-alkylation of a methyl group on N-heteroaromatic compounds, including pyridine, pyrimidine, pyrazine, quinoline, quinoxaline, and isoquinoline, using alcohols based on a hydrogen-borrowing process with [Cp*IrCl2]2… read more here.
Keywords: group heteroaromatic; methyl group; heteroaromatic compounds; alkylation methyl ... See more keywords
α-C-H Alkylation of Methyl Sulfides with Alkenes by a Scandium Catalyst.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b11245
Abstract: The C-H addition of sulfides to alkenes is an atom-efficient route for the functionalization and modification of sulfide compounds through C-C bond formation, but this transformation is highly challenging. We report here the regioselective α-C(sp3)-H… read more here.
Keywords: methyl sulfides; scandium catalyst; alkylation methyl; sulfides alkenes ... See more keywords