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Published in 2020 at "Reaction Kinetics, Mechanisms and Catalysis"
DOI: 10.1007/s11144-020-01760-5
Abstract: The heterogeneously catalyzed gas phase alkylation of m -cresol with methanol to 2,3,5-trimethylphenol, a precursor for vitamin E, on acidic zeolites and zirconium oxide-based catalysts was investigated. The influence of different acidic centers and of…
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Keywords:
phenol derivatives;
catalyzed zeolites;
derivatives catalyzed;
zeolites zirconia ... See more keywords
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Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc07305a
Abstract: A Cu-catalyzed O-alkylation of phenol derivatives using alkylsilyl peroxides as alkyl radical precursors is described. The reaction proceeds smoothly under mild reaction conditions and the use of two different ligands with a Cu catalyst provides…
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Keywords:
phenol derivatives;
catalyzed alkylation;
alkylsilyl peroxides;
alkylation phenol ... See more keywords
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Published in 2019 at "Catalysts"
DOI: 10.3390/catal9020202
Abstract: Using polyethylene glycol as a mesoporous soft template, a series of hierarchically porous ZSM-5 zeolites were prepared. X-ray diffraction, infrared spectroscopy, N2 adsorption–desorption, and transmission electron microscopy results demonstrated that the resultant materials contained a…
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Keywords:
hierarchical zsm;
phenol tert;
tert butanol;
alkylation phenol ... See more keywords