Ni-Catalyzed Enantioselective Allylic Alkylation of H-Phosphinates.
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DOI: 10.1021/acs.orglett.1c02986
Abstract: The asymmetric synthesis of P-stereogenic phosphinates through allylic alkylation of H-phosphinates has been developed. With H-phosphinates and allylic acetates as the starting materials, a variety of allylic P-chiral phosphinates were accessed in high enantioselectivities of… read more here.
Keywords: alkylation phosphinates; enantioselective allylic; catalyzed enantioselective; allylic alkylation ... See more keywords