A Germanium Catalyst Accelerates the Photoredox α-C(sp3)-H Alkylation of Primary Amines.
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DOI: 10.1021/acs.orglett.2c00871
Abstract: Site-selective C(sp3)-H functionalizations using photoredox catalysis (PC) and hydrogen atom transfer (HAT) catalysis have received increasing attention. Here, we report a Ph2GeCl2 cocatalyst that greatly improves the yield of α-C(sp3)-H alkylation of primary amines catalyzed… read more here.
Keywords: catalyst accelerates; germanium catalyst; alkylation primary; sp3 alkylation ... See more keywords