Regioselective Alkylative Cross-Coupling of Remote Unactivated C(sp3)-H Bonds.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b07014
Abstract: The functionalization of unactivated C(sp3)-H bonds poses a significant challenge due to their ubiquity and relative similarity in most organic frameworks. Herein, we describe the use of a combined photoredox and nickel catalytic system for… read more here.
Keywords: unactivated sp3; sp3 bonds; alkylative cross; regioselective alkylative ... See more keywords
N-Heterocyclic carbene-chromium-catalyzed alkylative cross-coupling of benzamide derivatives with aliphatic bromides.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc05026k
Abstract: Described here is a chromium-catalyzed alkylative cross-coupling of benzamide derivatives with aliphatic electrophiles under mild conditions. This reaction was promoted by a low-cost and air-stable chromium(iii) chloride salt combined with an N-heterocyclic carbene ligand and… read more here.
Keywords: chromium catalyzed; coupling benzamide; catalyzed alkylative; chromium ... See more keywords