The Formation of C-C or C-N Bonds via the Copper-Catalyzed Coupling of Alkylsilyl Peroxides and Organosilicon Compounds: A Route to Perfluoroalkylation.
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DOI: 10.1021/acs.orglett.1c00215
Abstract: The copper-catalyzed selective cleavage of alkylsilyl peroxides and the subsequent formation of carbon-carbon or carbon-nitrogen bonds with organosilicon compounds are described. The reaction proceeds under mild conditions and exhibits a broad substrate scope with respect… read more here.
Keywords: carbon; alkylsilyl; alkylsilyl peroxides; organosilicon compounds ... See more keywords