Conformationally Rigid Cyclic Tungsten Bis-Alkyne Complexes Derived from 1,1’-Dialkynylferrocenes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.05.048
Abstract: Abstract In exploring the conformational behavior of cyclic tungsten bis-alkyne complexes, two dialkynylamides (14a and 14c) and two dialkynylesters (14b and 14d) derived from 1,1’-ferrocenedicarboxylic acid were prepared. They were subsequently reacted with W(CO)3(dmtc)2 to… read more here.
Keywords: bis alkyne; conformation; alkyne complexes; tungsten bis ... See more keywords
Design and chiroptical properties of a water-soluble and violet-blue emissive alkyne template
Sign Up to like & getrecommendations! Published in 2017 at "Synthetic Metals"
DOI: 10.1016/j.synthmet.2017.10.008
Abstract: Abstract Circular dichroism (CD) and circular polarized luminescence (CPL) are useful for various applications. However, it is difficult to achieve excellent CD and CPL in differently polar solvents simultaneously. This work provides a simple but… read more here.
Keywords: water; water soluble; alkyne; chiroptical properties ... See more keywords
Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes
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DOI: 10.1021/acs.organomet.7b00668
Abstract: Gold(I) acetylide and σ,π-digold(I) alkyne complexes derived from one prototypical 1,6-enyne and from 7-ethynyl-1,3,5-cycloheptatriene have been prepared and structurally characterized. Their possible role in gold(I)-catalyzed cycloisomerizations has been studied by experiment and by DFT calculations.… read more here.
Keywords: role digold; alkyne complexes; digold alkyne; reactions enynes ... See more keywords
Cell-Free Biosynthesis of Lysine-Derived Unnatural Amino Acids with Chloro, Alkene, and Alkyne Groups.
Sign Up to like & getrecommendations! Published in 2023 at "ACS synthetic biology"
DOI: 10.1021/acssynbio.3c00132
Abstract: Crude extract-based cell-free expression systems have been used to produce natural products by reconstitution of their biosynthetic pathways in vitro. However, the chemical scope of cell-free synthesized natural compounds is still limited, which is partially… read more here.
Keywords: cell; biosynthesis; alkyne; cell free ... See more keywords