Stable Fluorinated Hybrid Microporous Material for the Efficient Separation of C2-C3 Alkyne/Alkene Mixtures.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00654
Abstract: The separation of C2-C3 alkyne/alkene mixtures is important but difficult work thanks to their similar physical and chemical properties. Crystalline porous materials with high alkyne adsorption and prominent separation selectivity of alkyne/alkene mixtures have been… read more here.
Keywords: hybrid microporous; alkene mixtures; alkyne alkene; separation alkyne ... See more keywords
Valence Localization in Alkyne and Alkene Adducts of Synthetic [Fe4S4]+ Clusters.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01353
Abstract: Reported herein are alkyne and alkene adducts of synthetic [Fe4S4]+ clusters that model intermediates and inhibitor-bound states in enzymes involved in isoprenoid biosynthesis. Treatment of the N-heterocyclic carbene-ligated cluster [(IMes)3Fe4S4(OEt2)][BArF4] (IMes = 1,3-dimesitylimidazol-2-ylidene; [BArF4]- =… read more here.
Keywords: fe4s4 clusters; alkyne alkene; adducts synthetic; alkene adducts ... See more keywords