Facile Synthesis of Triazoles using Electrospray-Deposited Copper Nanomaterials to Catalyze Azide-Alkyne Cycloaddition (AAC) Click Reactions.
Sign Up to like & getrecommendations! Published in 2022 at "ChemPlusChem"
DOI: 10.1002/cplu.202200252
Abstract: Electrospray deposition of copper salt-containing microdroplets onto the liquid surface of an electrically grounded reaction mixture leads to the formation of Cu nanoclusters, which then catalyze the azide-alkyne cycloaddition (AAC) reaction to form triazoles. This… read more here.
Keywords: catalyze azide; copper; cycloaddition aac; reaction ... See more keywords
Post‐functionalization of Organoboranes by Cu‐Catalyzed Azide Alkyne [3+2]‐Cycloaddition Reaction
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202400580
Abstract: The copper‐catalyzed azide alkyne [3+2]‐cycloaddition (CuAAC) reaction of organoboranes represents an attractive area of research within the field of click chemistry, with diverse applications in organic synthesis, medicinal chemistry, or materials science. Despite the potential… read more here.
Keywords: reaction; chemistry; alkyne cycloaddition; catalyzed azide ... See more keywords
A Peerless Aproach: Organophotoredox/Cu(I) Catalyzed, Regioselective, Visible Light Facilitated, Click Synthesis of 1,2,3-Triazoles via Azide–Alkyne [3 + 2] Cycloaddition
Sign Up to like & getrecommendations! Published in 2017 at "Catalysis Letters"
DOI: 10.1007/s10562-017-2156-8
Abstract: A visible light initiated, mild, one pot, multicomponent copper catalyzed azide alkyne [3 + 2] cycloaddition in the presence of organo photoredox catalyst Eosin Y using EtOH:H2O as reaction medium for the synthesis of substituted 1,2,3-triazoles is… read more here.
Keywords: alkyne cycloaddition; visible light; azide alkyne; light ... See more keywords
Copper-catalyzed azide–alkyne cycloaddition (CuAAC) under mild condition in water: Synthesis, catalytic application and biological activities
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.09.024
Abstract: Abstract A series of Cu-N-heterocyclic carbene (Cu-NHC) complexes, 3a-c , were synthesized and characterized by spectroscopic methods such as NMR, HRMS and elemental analysis. The performance of these (Cu-NHC) complexes, 3a-c showed excellent activity in… read more here.
Keywords: cycloaddition; alkyne cycloaddition; azide alkyne; catalyzed azide ... See more keywords
Copper-incorporated porous organic polymer as efficient and recyclable catalyst for azide-alkyne cycloaddition
Sign Up to like & getrecommendations! Published in 2021 at "Microporous and Mesoporous Materials"
DOI: 10.1016/j.micromeso.2020.110671
Abstract: Abstract Porous organic polymers (POPs) have attracted great attention in recent years as promising materials for heterogeneous metal catalysis. Herein, we report the facile synthesis of [2,6-bis(1,2,3-triazol-4-yl)pyridine] (BTP) functionalized porous organic polymer (PBPTP) through thiophene-based… read more here.
Keywords: azide alkyne; pbptp; organic polymer; porous organic ... See more keywords
Bioactive Polymeric Scaffolds: Multivalent Functionalization by Thermal Azide–Alkyne Cycloaddition with Alkynyl Dicarbamates
Sign Up to like & getrecommendations! Published in 2025 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.5c00038
Abstract: Multivalency enables interactions with higher affinities and specificities than monovalent interactions. The strategy exploited by nature to modulate biorecognition has inspired the design of multivalent conjugates with therapeutic properties. However, chemical functionalization often requires coupling… read more here.
Keywords: alkyne cycloaddition; alkynyl dicarbamates; multivalent functionalization; functionalization ... See more keywords
Hexavanadate-Organogold(I) Hybrid Compounds: Synthesis by the Azide-Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02621
Abstract: The fully oxidized Lindqvist-type hexavanadate compounds decorated by phosphine-derivatized Au(I) moieties oriented in a transoid fashion (n-Bu4N)2[V6O13{(OCH2)3CCH2(N3C2C6H5)AuP(C6H4OMe)3}2] (POMNAu) and (n-Bu4N)2[V6O13{(OCH2)3CCH2OCH2(C2N3H)AuP(C6H4OMe)3}2] (POMCAu) have been prepared by azide-alkyne cycloaddition reactions and characterized by various techniques, including NMR,… read more here.
Keywords: hexavanadate organogold; alkyne cycloaddition; azide alkyne; density ... See more keywords
Rhodium-Catalyzed Azide-Alkyne Cycloaddition of Internal Ynamides: Regioselective Assembly of 5-Amino-triazoles under Mild Conditions
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.7b02558
Abstract: A rhodium-catalyzed azide–alkyne cycloaddition of internal ynamides is described. The reaction could be performed in a wide range of solvents, including aqueous media, under mild conditions without careful exclusion of air and moisture, giving a… read more here.
Keywords: cycloaddition; cycloaddition internal; rhodium catalyzed; alkyne cycloaddition ... See more keywords
Enantioselective Rh-Catalyzed Azide-Internal-Alkyne Cycloaddition for the Construction of Axially Chiral 1,2,3-Triazoles.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c01985
Abstract: Significant advances have been achieved for the construction of chiral skeletons containing 1,2,3-triazoles via transition-metal-catalyzed asymmetric azide-alkyne cycloaddition; however, most of them have been limited to terminal alkynes in the synthesis of central chirality via… read more here.
Keywords: azide internal; alkyne cycloaddition; catalyzed azide; axially chiral ... See more keywords
Oxidation-Controlled, Strain-Promoted Tellurophene-Alkyne Cycloaddition (OSTAC): A Bioorthogonal Tellurophene-Dependent Conjugation Reaction.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c07275
Abstract: Tellurophene-bearing small molecules have emerged as valuable tools for localizing cellular activities in vivo using mass cytometry. To broaden the utility of tellurophenes in chemical biology, we have developed a bioorthogonal reaction to facilitate tagging… read more here.
Keywords: reaction; alkyne cycloaddition; tellurophene; biology ... See more keywords
Regioselective Zn(OAc)2-catalyzed azide–alkyne cycloaddition in water: the green click-chemistry
Sign Up to like & getrecommendations! Published in 2017 at "Organic chemistry frontiers"
DOI: 10.1039/c6qo00787b
Abstract: A new method of azide–alkyne cycloaddition (AAC) in the presence of Zn(OAc)2 as an inexpensive and environmentally friendly catalyst in neat water has been developed. The proposed methodology has been applied for the synthesis of… read more here.
Keywords: water; alkyne cycloaddition; regioselective oac; chemistry ... See more keywords