Alkyne dimerization-hydroarylation to form pentasubstituted 1,3-dienes via binuclear nickel catalysis
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DOI: 10.1038/s41467-025-58398-x
Abstract: Mono-metallic catalysts dominate in homogeneous catalysis, wherein all the element steps generally occur on one metal site. Inspired from bimetallic active sites in both enzymes and heterogeneous catalysts, the development of binuclear catalysis can offer… read more here.
Keywords: alkyne dimerization; mono metallic; hydroarylation; catalysis ... See more keywords
One-pot synthesis of α,β-unsaturated ketones through sequential alkyne dimerization/hydration reactions using the Hoveyda–Grubbs catalyst
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d1nj02410h
Abstract: The combination of HG2/PCy3 and CCl3COOH/p-TsOH·H2O through one-pot alkyne dimerization/hydration reactions gave α,β-unsaturated ketones in quantitative yields within 2.5–4 h. read more here.
Keywords: dimerization hydration; alkyne dimerization; hydration reactions; unsaturated ketones ... See more keywords