Rhodium(I) Complexes with Ligands Based on N-Heterocyclic Carbene and Hemilabile Pyridine Donors as Highly E Stereoselective Alkyne Hydrosilylation Catalysts
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00361
Abstract: Cationic rhodium(I) complexes containing picolyl-NHC (NHC = N-heterocyclic carbene) ligands that differ in the substitution at the 6-position of the pyridine donor serve as efficient E-selective alkyne hydrosilylation catalyst precursors. Particularly, when the steric hindrance… read more here.
Keywords: pyridine; rhodium complexes; alkyne hydrosilylation; hydrosilylation ... See more keywords
Cobalt-catalyzed alkyne hydrosilylation as a new frontier to selectively access silyl-hydrocarbons.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc06214j
Abstract: The hydrosilylation of alkynes is a chief chemical method for accessing a range of alkenylsilanes, which can be derivatized to obtain value-added hydrocarbons and utilized in diverse applications. While noble metal-based catalytic procedures have shown… read more here.
Keywords: cobalt catalyzed; hydrosilylation; catalyzed alkyne; new frontier ... See more keywords