Pairing d-Band Center of Metal Sites with π-Orbital of Alkynes for Efficient Electrocatalytic Alkyne Semi-Hydrogenation.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202205845
Abstract: Electrocatalytic alkyne semi-hydrogenation has attracted ever-growing attention as a promising alternative to traditional thermocatalytic hydrogenation. However, the correlation between the structure of active sites and electrocatalytic performance still remains elusive. Herein, the energy difference (∆ε)… read more here.
Keywords: hydrogenation; semi hydrogenation; alkyne semi; electrocatalytic alkyne ... See more keywords
Converting copper sulfide to copper with surface sulfur for electrocatalytic alkyne semi-hydrogenation with water
Sign Up to like & getrecommendations! Published in 2021 at "Nature Communications"
DOI: 10.1038/s41467-021-24059-y
Abstract: Electrocatalytic alkyne semi-hydrogenation to alkenes with water as the hydrogen source using a low-cost noble-metal-free catalyst is highly desirable but challenging because of their over-hydrogenation to undesired alkanes. Here, we propose that an ideal catalyst… read more here.
Keywords: electrocatalytic alkyne; alkyne semi; semi hydrogenation; hydrogenation ... See more keywords