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Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc07560c
Abstract: Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides to form highly substituted and functionalized alkenyl iodides has been developed. The reaction involves radical-mediated formal alkyne insertion into the carbon-nickel bond and carbon-iodine reductive elimination facilitated…
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Keywords:
catalyzed intermolecular;
aryl iodides;
carboiodination alkynes;
alkynes aryl ... See more keywords
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Published in 2017 at "Chemistry Letters"
DOI: 10.1246/cl.170961
Abstract: The hydrogenative cross-coupling of internal alkynes and aryl iodides by palladium/copper cooperative catalysis furnished a range of triarylethenes in moderate to good yield and stereoselectivity. Under the applied catalytic conditions, various functional groups, including silylether,…
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Keywords:
hydrogenative cross;
internal alkynes;
aryl iodides;
alkynes aryl ... See more keywords