Catalyst-free hydrothiolation of alkynes with dithiocarbamic acids.
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DOI: 10.1039/c8cc09726g
Abstract: A highly regio- and stereocontrolled procedure for the synthesis of vinyl dithiocarbamates via catalyst-free hydrothiolation of unactivated alkynes with in situ prepared dithiocarbamic acids with total atom economy is reported. While unactivated terminal alkynes afforded… read more here.
Keywords: dithiocarbamic acids; free hydrothiolation; hydrothiolation alkynes; alkynes dithiocarbamic ... See more keywords