Iron(II) Bis(acetylide) Complexes as Key Intermediates in the Catalytic Hydrofunctionalization of Terminal Alkynes
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DOI: 10.1021/acscatal.8b01942
Abstract: Nonclassical iron(II) polyhydride complexes supported by PNP-pincer ligands were found to be very active catalysts for the Z-selective hydroboration and head-to-head dimerization of terminal alkynes. Iron(II) bis(acetylide) complexes are identified as catalytically active species in… read more here.
Keywords: iron bis; key intermediates; terminal alkynes; alkynes iron ... See more keywords