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Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b07418
Abstract: We report the synthesis and reactivity of Zr complexes supported by a 9,10-anthracenediyl-linked bisphenoxide ligand, L. ZrIVLBn2 (1) undergoes facile photolytic reduction with concomitant formation of bibenzyl and ZrIVL(THF)3 (2), which displays a two-electron reduced…
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Keywords:
alkynes nitriles;
supported noninnocent;
anthracene;
coupling supported ... See more keywords
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Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/d0qo01246g
Abstract: Density functional theory (DFT) calculations were performed to gain an in-depth mechanistic understanding of the Rh(I)-catalyzed transannulation of 1,2,3-thiadiazoles with alkenes, alkynes, and nitriles. Computational results indicate that the denitrogenation of 1,2,3-thiadiazoles promoted by the…
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Keywords:
transannulation thiadiazoles;
alkynes nitriles;
catalyzed transannulation;
thiadiazoles alkenes ... See more keywords