Synthesis of (E)‐β‐Iodovinyl Sulfones via HI‐mediated Vicinal Iodosulfonylation of Alkynes with Sodium Sulfinates
Sign Up to like & getrecommendations! Published in 2024 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202400059
Abstract: Hydroiodic acid‐mediated vicinal iodosulfonylation reaction of alkynes with sodium sulfinates is proposed for the synthesis of (E)‐β‐iodovinyl sulfones. The method is easy to operate, environmentally friendly, using inexpensive and easily available raw materials, and giving… read more here.
Keywords: alkynes sodium; vicinal iodosulfonylation; synthesis iodovinyl; iodovinyl sulfones ... See more keywords
Copper-Catalyzed Disulfonation of Terminal Alkynes with Sodium Arylsulfinates.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c00575
Abstract: A novel and direct disulfonylation reaction of commercially available terminal alkynes under copper(I)/bromodifluoroacetate cocatalyst has been realized. This protocol provides a facile and practical pathway to selectively access (E)-1,2-disulfonylethenes, in which features good functional group… read more here.
Keywords: catalyzed disulfonation; copper catalyzed; terminal alkynes; alkynes sodium ... See more keywords
Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28114436
Abstract: The subject of this investigation is a new method for the construction of sulfonylated heterocycles which overcomes the limitations of classical approaches using a cheap feedstock sulfonylating agent, especially under photocatalyst- and metal-free conditions. read more here.
Keywords: photocatalyst free; cascade cyclization; free cascade; alkynes sodium ... See more keywords