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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03092
Abstract: Stereoselective difunctionalizations of the terminal and internal alkynes with various sulfinates and isocyanides have been achieved to prepare (Z)-/(E)-β-sulfonylacrylamides. The (Z)-β-sulfonylacrylamides were generated via a one-pot process that involves the reaction of terminal alkynes with…
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Keywords:
alkynes sulfinates;
synthesis sulfonylacrylamides;
sulfonylacrylamides via;
sulfinates isocyanides ... See more keywords
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1
Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03985
Abstract: An unprecedented electrochemical three-component reaction of phenylacetylene, sulfinate, and N-(formyl)anilide was discovered. The transformation occurs in an undivided cell with a graphite anode and cathode in DMF in the presence of tetrabutylammonium iodide as an…
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Keywords:
alkynes sulfinates;
electrochemical decarbonylative;
formyl anilides;
aminosulfonylation alkynes ... See more keywords