Tandem Cross-Coupling of Alkynyl Sulfides and Alkynyl Sulfoxides/[3,3]-Sulfonium Rearrangement to Construct Tetrasubstituted Furans.
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DOI: 10.1021/acs.orglett.1c04242
Abstract: In the presence of boron trifluoride, a variety of alkynyl sulfides and alkynyl sulfoxides undergo tandem cross-coupling/[3,3]-sulfonium rearrangement followed by 5-exo-dig heterocyclization. The strategy provides concise access to novel tetrasubstituted furans in good to high… read more here.
Keywords: cross coupling; alkynyl sulfoxides; alkynyl sulfides; sulfides alkynyl ... See more keywords
Cobalt-catalyzed cross-electrophile coupling of alkynyl sulfides with unactivated chlorosilanes
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DOI: 10.1038/s41467-024-48873-2
Abstract: Herein, we disclose a highly efficient cobalt-catalyzed cross-electrophile alkynylation of a broad range of unactivated chlorosilanes with alkynyl sulfides as a stable and practical alkynyl electrophiles. Strategically, employing easily synthesized alkynyl sulfides as alkynyl precursors… read more here.
Keywords: cross electrophile; alkynyl sulfides; catalyzed cross; cobalt catalyzed ... See more keywords
One-step synthesis of benzo[b]thiophenes by aryne reaction with alkynyl sulfides†
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DOI: 10.1039/d0sc04450d
Abstract: An aryne reaction with alkynyl sulfides affording benzo[b]thiophenes is disclosed. A wide range of 3-substituted benzothiophenes were synthesized from easily available o-silylaryl triflates and alkynyl sulfides in a one-step intermolecular manner. The synthesis of diverse… read more here.
Keywords: aryne reaction; alkynyl sulfides; one step; reaction alkynyl ... See more keywords
anti-Carbometalation of Alkynyl Sulfides Using Indium Tribromide and Ketene Silyl Acetals
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DOI: 10.1246/cl.200400
Abstract: We developed the regioselective anti-carbometalation of alkynyl sulfides via the use of InBr3 and organosilicon nucleophiles to give β-mercaptoalkenylindium compounds. The structure of β-mercaptoal... read more here.
Keywords: anti carbometalation; using indium; alkynyl sulfides; sulfides using ... See more keywords