Copper-Catalyzed Hydroamination of Allenes: from Mechanistic Understanding to Methodology Development
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DOI: 10.1021/acscatal.7b00911
Abstract: Experimental and theoretical mechanistic studies on the Cu(OTf)2-catalyzed hydroamination reaction of terminal allenes with secondary amines reveal that in situ generated cationic Cu(I) is the catalytically active species and explain the observed regio- and stereoselectivity… read more here.
Keywords: methodology; copper catalyzed; catalyzed hydroamination; allenes mechanistic ... See more keywords