Diversification reactions of γ-silyl allenyl esters: selective conversion to all-carbon quaternary centers and γ-allene dicarbinols.
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DOI: 10.1039/c7cc01708a
Abstract: The unique reactivity of γ-silyl allenyl esters is described. Taking advantage of the silyl group as a fluoride acceptor, these allenoates readily underwent addition to a variety of electrophiles to selectively yield products with all-carbon… read more here.
Keywords: silyl allenyl; allenyl esters; carbon quaternary; reactions silyl ... See more keywords