Divergent Asymmetric Total Syntheses of (-)-Alloaristoteline and (+)-Aristoteline via Directed Indolization Strategies.
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DOI: 10.1021/acs.orglett.3c01224
Abstract: A divergent asymmetric synthetic route to (-)-alloaristoteline and (+)-aristoteline is described. The key doubly bridged tricyclic enol triflate common intermediate prepared via enantioselective deprotonation and stepwise annulation was successfully bifurcated to complete the first completely… read more here.
Keywords: directed indolization; total syntheses; alloaristoteline aristoteline; asymmetric total ... See more keywords