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Published in 2020 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2020.152688
Abstract: Abstract Given the necessity of sacrificial reductants in various biomimetic aerobic oxygenations, alloxan-catalyzed aerobic redox system for one-pot atom-economic synthesis of sulfinyl-functionalized benzimidazoles was developed by ingeniously binding both the substrate sulfide and sacrificial reductant.…
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Keywords:
alloxan catalyzed;
synthesis sulfinyl;
atom economic;
pot atom ... See more keywords
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Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b04508
Abstract: Inspired by biological flavin catalysis, the nonionic alloxan derivatives were applied as the biomimetic catalysts for various oxidations, catalyzing oxidations of sulfides and amines with hydrogen peroxide or molecular oxygen under mild conditions with high…
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Keywords:
alloxan catalyzed;
molecular oxygen;
alloxan;
hydrogen peroxide ... See more keywords