Biomimetic alloxan-catalyzed intramolecular redox reaction with O2: One-pot atom-economic synthesis of sulfinyl-functionalized benzimidazoles
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DOI: 10.1016/j.tetlet.2020.152688
Abstract: Abstract Given the necessity of sacrificial reductants in various biomimetic aerobic oxygenations, alloxan-catalyzed aerobic redox system for one-pot atom-economic synthesis of sulfinyl-functionalized benzimidazoles was developed by ingeniously binding both the substrate sulfide and sacrificial reductant.… read more here.
Keywords: alloxan catalyzed; synthesis sulfinyl; atom economic; pot atom ... See more keywords
Alloxan-Catalyzed Biomimetic Oxidations with Hydrogen Peroxide or Molecular Oxygen
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DOI: 10.1021/acscatal.9b04508
Abstract: Inspired by biological flavin catalysis, the nonionic alloxan derivatives were applied as the biomimetic catalysts for various oxidations, catalyzing oxidations of sulfides and amines with hydrogen peroxide or molecular oxygen under mild conditions with high… read more here.
Keywords: alloxan catalyzed; molecular oxygen; alloxan; hydrogen peroxide ... See more keywords