Defining a Materials Database for the Design of Copper Binary Alloy Catalysts for Electrochemical CO2 Conversion.
Sign Up to like & getrecommendations! Published in 2018 at "Advanced materials"
DOI: 10.1002/adma.201704717
Abstract: While Cu electrodes are a versatile material in the electrochemical production of desired hydrocarbon fuels, Cu binary alloy electrodes are recently proposed to further tune reaction directionality and, more importantly, overcome the intrinsic limitation of… read more here.
Keywords: binary alloy; alloy; co2 conversion; alloy catalysts ... See more keywords
Applications of Machine Learning in Alloy Catalysts: Rational Selection and Future Development of Descriptors
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Science"
DOI: 10.1002/advs.202106043
Abstract: At present, alloys have broad application prospects in heterogeneous catalysis, due to their various catalytic active sites produced by their vast element combinations and complex geometric structures. However, it is the diverse variables of alloys… read more here.
Keywords: rational selection; machine; development; machine learning ... See more keywords
Alloy Catalysts for Electrocatalytic CO2 Reduction.
Sign Up to like & getrecommendations! Published in 2023 at "Small methods"
DOI: 10.1002/smtd.202300482
Abstract: CO2 conversion is an anticipated route to resolve the energy crisis and environmental pollution, in which electrocatalysis is one of the technologies closest to industrialization. Alloy catalysts are promising candidates for electrocatalysis, and the high… read more here.
Keywords: electrocatalytic co2; catalysts electrocatalytic; co2 reduction; alloy catalysts ... See more keywords
Pt-Ni alloy catalysts for highly selective anti-Markovnikov alkene hydrosilylation
Sign Up to like & getrecommendations! Published in 2018 at "Science China Materials"
DOI: 10.1007/s40843-018-9282-1
Abstract: 摘要铂基催化剂已广泛应用于烯烃的硅氢加成反应, 但贵金属铂因其稀有而价高, 成为其工业化应用的障碍. 为了降低成本和提高原子效率, 我们采用了廉价的镍金属来代替金属铂. 本文合成了一系列具有可调成分和形貌的双金属铂镍催化剂, 发现其在温和条件下对烯烃的硅氢加成反应表现出优越的活性和选择性. 此外, 还发现八面体的铂镍纳米合金不仅能应用于具有不同的官能团烯烃, 而且还有利于有机硅和硅烷偶联剂的绿色化学制备, 开发出更多的新产品. read more here.
Keywords: highly selective; anti markovnikov; alloy catalysts; catalysts highly ... See more keywords
Effect of rare-earth elements in Pd ternary alloy catalysts on activity toward oxygen reduction reaction
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DOI: 10.1016/j.cattod.2019.12.022
Abstract: Abstract To enhance the catalytic activity of Pd toward the oxygen reduction reaction (ORR), transition metals are alloyed with Pd. This changes the electronic structure of Pd because alloyed transition metal induces a lattice mismatch… read more here.
Keywords: earth elements; rare earth; activity; alloy catalysts ... See more keywords
Synthetic natural gas production from CO2 and renewable H2: Towards large-scale production of Ni–Fe alloy catalysts for commercialization
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Cleaner Production"
DOI: 10.1016/j.jclepro.2020.121720
Abstract: Abstract Synthetic natural gas (SNG) is one of the promising energy carriers for the excessive electricity generated from variable renewable energy sources. SNG production from renewable H2 and CO2 via catalytic CO2 methanation has gained… read more here.
Keywords: synthetic natural; production; alloy catalysts; co2 ... See more keywords
Comprehensive Study on Ni- or Ir-Based Alloy Catalysts in the Hydrogenation of Olefins and Mechanistic Insight
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DOI: 10.1021/acscatal.0c04615
Abstract: Metal-alloyed atomic catalysts such as single-atom alloys have attracted much attention due to their high atom economy and their unique catalytic properties. Recently, we found that a SiO2-supporte... read more here.
Keywords: comprehensive study; study based; hydrogenation olefins; alloy catalysts ... See more keywords
Hydrogen Production via Efficient Formic Acid Decomposition: Engineering the Surface Structure of Pd-Based Alloy Catalysts by Design
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DOI: 10.1021/acscatal.8b03485
Abstract: Improving the activity and selectivity of Pd-based alloy catalysts for hydrogen production from formic acid decomposition is still a challenge. We have performed a comprehensive study, on the basis of available experimental data, of the… read more here.
Keywords: alloy catalysts; formic acid; based alloy; acid decomposition ... See more keywords
Highly Efficient Supported Palladium–Gold Alloy Catalysts for Hydrogen Storage Based on Ammonium Bicarbonate/Formate Redox Cycle
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b04698
Abstract: We have developed supported Pd–Au alloy catalysts for reversible hydrogen storage–release process with high efficiency based on the reversible reactions involving ammonium formate and bicarbonate. Supported Pd–Au random alloy catalysts exhibited a superior activity than… read more here.
Keywords: hydrogen storage; formate; ammonium; alloy catalysts ... See more keywords
The emergence of Heusler alloy catalysts
Sign Up to like & getrecommendations! Published in 2019 at "Science and Technology of Advanced Materials"
DOI: 10.1080/14686996.2019.1598238
Abstract: ABSTRACT For over a century, Heusler alloys (X 2 YZ; X, Y: transition metals, Z: typical metals) have attracted attention as magnetic materials. Nowadays, they are also popular as thermoelectric and shape memory materials. However,… read more here.
Keywords: alloy; alloy catalysts; heusler alloys; emergence heusler ... See more keywords
The Hydrogenation of Crotonaldehyde on PdCu Single Atom Alloy Catalysts
Sign Up to like & getrecommendations! Published in 2023 at "Nanomaterials"
DOI: 10.3390/nano13081434
Abstract: Recyclable PdCu single atom alloys supported on Al2O3 were applied to the selective hydrogenation of crotonaldehyde to elucidate the minimum number of Pd atoms required to facilitate the sustainable transformation of an α,β-unsaturated carbonyl molecule.… read more here.
Keywords: single atom; alloy catalysts; atom alloy; pdcu single ... See more keywords