Solar light induced transformation mechanism of allyl alcohol to monocarbonyl and dicarbonyl compounds on different TiO2: A combined experimental and theoretical investigation.
Sign Up to like & getrecommendations! Published in 2019 at "Chemosphere"
DOI: 10.1016/j.chemosphere.2019.05.219
Abstract: Enols are an important group of photochemical precursors of atmospheric carbonyl compounds. However, the transformation mechanism is not fully understood. In this study, the photo-induced transformation of a typical enol, allyl alcohol, to carbonyl compounds… read more here.
Keywords: allyl alcohol; dicarbonyl compounds; monocarbonyl; transformation ... See more keywords
Polylactide stereocomplex bearing vinyl groups at chain ends prepared by allyl alcohol, malic acid, and citric acid
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Degradation and Stability"
DOI: 10.1016/j.polymdegradstab.2020.109311
Abstract: Abstract In order to develop functional polymers using polylactide (PLA), it has been paid attention to use various initiators for ring-opening polymerization, because the polymer backbone could not be modified if a stereocomplex formation was… read more here.
Keywords: allyl alcohol; chain ends; acid; malic acid ... See more keywords
Total synthesis of (R)-tylophorine by using an asymmetric hydrogenation of the allyl alcohol
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2018.04.052
Abstract: Abstract An efficient synthesis of naturally occurring (R)-tylophorine is described. The alkaloid was prepared in seven steps from a known phenanthryl aldehyde with an overall yield of 14.2%. Asymmetric hydrogenation of an allyl alcohol was… read more here.
Keywords: allyl alcohol; asymmetric hydrogenation; tylophorine; hydrogenation allyl ... See more keywords
Poly(allyl alcohol) Homo- and Block Polymers by Postpolymerization Reduction of an Activated Polyacrylamide.
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DOI: 10.1021/jacs.8b07542
Abstract: Direct polymerization of allyl alcohol generally results in low molar mass oligomers or highly branched or cross-linked structures, and the properties and applications of linear, high molar mass poly(allyl alcohol) (PAA) are relatively unexplored. Such… read more here.
Keywords: allyl alcohol; reduction; activated polyacrylamide; poly allyl ... See more keywords
The salt-free nickel-catalysed α-allylation reaction of ketones with allyl alcohol and diallylether
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DOI: 10.1039/c9gc03619a
Abstract: The nickel-catalysed α-allylation of ketones with allyl alcohol and diallylether has been performed under neutral conditions. As no base is involved, the products are synthesized without salts as side products. The dppf/Ni(cod)2 catalytic system in… read more here.
Keywords: catalysed allylation; allyl alcohol; ketones allyl; nickel catalysed ... See more keywords
Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst
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DOI: 10.1055/s-0037-1612010
Abstract: The dehydrative allylation from allyl alcohol with amines to generate various allyl amines by MoO3/TiO2 solid catalyst is described. The catalyst can be reused at least three times without a decrease of activity. read more here.
Keywords: dehydrative allylation; allyl alcohol; catalyst;