Traceless Directing-Group Strategy in the Ru-Catalyzed, Formal [3 + 3] Annulation of Anilines with Allyl Alcohols: A One-Pot, Domino Approach for the Synthesis of Quinolines.
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DOI: 10.1021/acs.orglett.7b00715
Abstract: A unique, ruthenium-catalyzed, [3 + 3] annulation of anilines with allyl alcohols in the synthesis of substituted quinolines is reported. The method employs a traceless directing group strategy in the proximal C-H bond activation and… read more here.
Keywords: directing group; anilines allyl; traceless directing; allyl alcohols ... See more keywords
Carboxylate-directed C–H allylation with allyl alcohols or ethers† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc01741g
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DOI: 10.1039/c8sc01741g
Abstract: A ruthenium-catalysed ortho-C–H allylation of benzoic acids is disclosed that makes use of unactivated allyl alcohols or seemingly inert allyl methyl ethers as allylating agents. read more here.
Keywords: directed allylation; allyl; allylation allyl; allyl alcohols ... See more keywords
Construction of pyrazolone analogues via rhodium-catalyzed C–H activation from pyrazolones and non-activated free allyl alcohols
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DOI: 10.1039/c9qo00504h
Abstract: Highly efficient rhodium(iii) catalysis was developed for obtaining structurally divergent pyrazolone analogues from pyrazolones and non-activated free allyl alcohols. read more here.
Keywords: activated free; non activated; allyl alcohols; free allyl ... See more keywords