Expanding the allyl analogy: accessing η3-P,B,P diphosphinoborane complexes of group 10.
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DOI: 10.1039/c8dt00058a
Abstract: Using the diphosphinoborane, (PPh2)2BMes (Mes = 2,4,6-Me3C6H3), we report the first examples of η3-P,B,P-ligated complexes using Ni(0) and Pt(ii). Reaction of (PPh2)2BMes with Ni(COD)2 or Pt(COD)Me2 (COD = 1,5-cyclooctadiene) results in gradual COD displacement to… read more here.
Keywords: expanding allyl; pph2 2bmes; cod; diphosphinoborane ... See more keywords