Direct, Mild, and General n-Bu4NBr-Catalyzed Aldehyde Allylsilylation with Allyl Chlorides.
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DOI: 10.1021/acs.orglett.7b03193
Abstract: A direct, mild, and general method for the enantioselective allylsilylation of aldehydes with allyl chlorides is reported. The reactions are effectively catalyzed by 5 mol % of n-Bu4NBr, and this rate acceleration allows the use… read more here.
Keywords: allylsilylation; allyl chlorides; mild general; direct mild ... See more keywords