Articles with "allyl iridium" as a keyword



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Intercepting a labile anti-π-allyl-iridium complex before its isomerization

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Published in 2021 at "Chem"

DOI: 10.1016/j.chempr.2021.02.022

Abstract: The stereodefined installation of chiral centers adjacent to thermodynamically unstable Z-olefins is a challenge in synthetic chemistry. In a recent work published in Science, You and coworkers reported an iridium-catalyzed, Z-retentive asymmetric allylic allylation with… read more here.

Keywords: intercepting labile; anti allyl; complex isomerization; labile anti ... See more keywords