Cationic allyl nickel complexes containing N,O-donor labile ligands: Synthesis and molecular characterisation
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DOI: 10.1016/j.molstruc.2019.01.045
Abstract: Abstract Three 2-iminofuran ligands 2-(N-2,6-diisopropylphenylformimino)furan (L1), 2-(N-2,6-dimethylphenylformimino)furan (L2) and 2-(N-4-methoxyphenylformimino)furan (L3) were obtained by condensation reactions of the respective anilines with furfural. The η3-allyl Ni(II) cationic complexes 1–3 have been synthesised by reacting [Ni(η3-C3H5)(μ-Br)]2 with… read more here.
Keywords: allyl nickel; donor labile; containing donor; nickel complexes ... See more keywords
Kinetics and Mechanism of Thermal Decomposition of Bis(η3-Allyl)Nickel Complexes
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DOI: 10.1134/s0023158419020150
Abstract: The kinetics of thermal decomposition of bis(η3-allyl) nickel complexes in various media is studied. The specific features of the mechanism are determined, including the combination of the stages of trans-cis isomerization of Niall2 and the… read more here.
Keywords: decomposition bis; allyl nickel; decomposition; thermal decomposition ... See more keywords