Enantioselective Rhodium-Catalyzed Allylation of Aliphatic Imines: Synthesis of Chiral C-Aliphatic Homoallylic Amines.
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DOI: 10.1021/acs.orglett.0c02069
Abstract: Reported herein is a method for the efficient syntheses of optically active 1-alkyl homoallylic amines in yields up to 95%, 13.5:1 dr, and 98% ee under mild, aqueous reaction conditions, via the Rh-catalyzed asymmetric allylation… read more here.
Keywords: catalyzed allylation; enantioselective rhodium; homoallylic amines; rhodium catalyzed ... See more keywords