Palladium-catalyzed meta-C-H allylation of arenes: A unique combination of pyrimidine-based template and hexafluoroisopropanol.
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DOI: 10.1021/jacs.0c05223
Abstract: Controlling remote selectivity and delivering novel functionalities at distal positions in arenes are an important endeavor in contemporary organic synthesis. In this vein, template engineering and mechanistic understanding of new functionalization strategies are essential for… read more here.
Keywords: allylation arenes; template; meta allylation; palladium ... See more keywords