Catalytic C-N and C-H Bond Activation: ortho-Allylation of Benzoic Acids with Allyl Amines.
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DOI: 10.1021/acs.orglett.8b01762
Abstract: A facile insertion of ruthenium into aromatic C-H and allylic C-N bonds are the key steps in a [Ru( p-cymene)Cl2]2-catalyzed ortho-C-H allylation of benzoic acids. This protocol allows drawing on the large pool of allylic… read more here.
Keywords: catalytic bond; benzoic acids; allylation benzoic; ortho allylation ... See more keywords