Palladium-catalysed α-allylation of chiral sulfinimines derived from symmetric cyclic ketones
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DOI: 10.1016/j.tetlet.2017.02.008
Abstract: Abstract A diastereoselective mono-allylation reaction at the α-position of symmetric cyclic ketones by using tert-butanesulfinamide as a chiral auxiliary is explored. Excellent yields and high diastereomeric ratios were achieved under palladium(0) catalysis in the presence… read more here.
Keywords: symmetric cyclic; catalysed allylation; allylation chiral; cyclic ketones ... See more keywords
Rh-Catalyzed diastereo- and linear-selective α-allylation of chiral cycloenamines
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DOI: 10.1039/d0qo01087a
Abstract: In this paper, a Rh-catalyzed diastereoselective α-allylation of cycloenamines is demonstrated. read more here.
Keywords: diastereo linear; selective allylation; allylation; catalyzed diastereo ... See more keywords