Intramolecular Umpolung Allylation of Imines.
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DOI: 10.1021/acs.orglett.8b02536
Abstract: An intramolecular umpolung allylation of imines is reported. This reaction occurs via the intermediacy of 2-azaallyl anions. It could proceed either under transition-metal-catalyzed conditions or under transition-metal-free conditions. Importantly, this approach afforded trans-3-vinyl-4-aminochromanes with high… read more here.
Keywords: intramolecular umpolung; umpolung allylation; allylation imines;