Iridium-Catalyzed Asymmetric Cascade Allylation/Retro-Claisen Reaction.
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DOI: 10.1021/jacs.2c08811
Abstract: An enantiomerically enriched 3-hydroxymethyl pentenal unit is one of the key structural cores in plenty of natural products and drug candidates with significant biological activities. However, very few synthetic methodologies for the facile construction of… read more here.
Keywords: allylation retro; reaction; catalyzed asymmetric; iridium catalyzed ... See more keywords