Ligand-Enabled Copper-Catalyzed Regio- and Stereoselective Allylboration of 1-Trifluoromethylalkenes.
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DOI: 10.1021/acs.orglett.2c03024
Abstract: A copper-catalyzed regio- and stereoselective allylboration of 1-trifluoromethylalkenes with bis(pinacolato)diboron (pinB-Bpin) and allylic chlorides has been developed to form functionalized trifluoromethylated products with high diastereoselectivity. The key to success is the judicious choice of Cs2CO3… read more here.
Keywords: stereoselective allylboration; catalyzed regio; allylboration trifluoromethylalkenes; regio stereoselective ... See more keywords