A Simplified Approach for Electrochemical Allylic Oxidation of Olefins
Sign Up to like & getrecommendations! Published in 2025 at "Helvetica Chimica Acta"
DOI: 10.1002/hlca.202500068
Abstract: A simple method for the electrochemical allylic oxidation of olefins to enones based on peroxide‐mediated C–H activation is presented. t‐Butyl hydroperoxide serves a dual role as mediator and oxygen source, avoiding the utilization of expensive… read more here.
Keywords: electrochemical allylic; simplified approach; allylic oxidation; oxidation ... See more keywords
A further step to sustainable palladium catalyzed oxidation: Allylic oxidation of alkenes in green solvents
Sign Up to like & getrecommendations! Published in 2021 at "Applied Catalysis A: General"
DOI: 10.1016/j.apcata.2021.118349
Abstract: Abstract The palladium catalyzed oxidation of alkenes with molecular oxygen is a synthetically important reaction which employs palladium catalysts in solution; therefore, a solvent plays a critical role for the process. In this study, we… read more here.
Keywords: oxidation; green solvents; palladium catalyzed; oxidation alkenes ... See more keywords
Increased selectivity for allylic oxidation of cyclohexene using TiO2 modified V2O5/MoO3 catalysts
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DOI: 10.1016/j.catcom.2017.05.023
Abstract: V2O5 and MoO3 mixed oxides supported by SiO2 were studied as the catalysts in the aqueous phase allylic oxidation of cyclohexene to unsaturated alcohol 2-cyclohexene-1-ol and unsaturated ketone 2-cyclohexene-1-one. The additional layer of TiO2 deposited… read more here.
Keywords: cyclohexene; v2o5 moo3; oxidation cyclohexene; allylic oxidation ... See more keywords
Immobilization of (l)-valine and (l)-valinol on SBA-15 nanoporous silica and their application as chiral heterogeneous ligands in the Cu-catalyzed asymmetric allylic oxidation of alkenes
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DOI: 10.1039/d1nj02580e
Abstract: Chiral heterogeneous ligands AL*-i-Pr-SBA-15 and AA*-i-Pr-SBA-15 were synthesized and then used in Cu-catalyzed asymmetric allylic oxidation of alkenes. Allylic esters with moderate enantiomeric excess and good yields were obtained. read more here.
Keywords: chiral heterogeneous; catalyzed asymmetric; asymmetric allylic; heterogeneous ligands ... See more keywords
Palladium-catalyzed Asymmetric Allylic C–H Oxidation for the Formal Synthesis of Gonytolide C
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DOI: 10.1246/cl.170406
Abstract: For the synthesis of Gonytolide C, an enantioselective intramolecular allylic C–H oxidation was applied to afford the chiral chroman framework in good yield and enantioselectivity, and the key step to obtain the lactone moiety was… read more here.
Keywords: gonytolide; palladium catalyzed; synthesis gonytolide; allylic oxidation ... See more keywords