Rh-Catalyzed Regio- and Enantioselective Allylic Phosphinylation.
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DOI: 10.1021/jacs.2c00239
Abstract: Transition-metal-catalyzed branched and enantioselective allylic substitution of monosubstituted precursors with carbon, nitrogen, oxygen, sulfur, and fluoride nucleophiles has been well-established. However, such a selective carbon-phosphorus bond formation has not been realized probably due to the… read more here.
Keywords: phosphine; catalyzed regio; allylic phosphinylation; enantioselective allylic ... See more keywords