Polyanionic Ligand Platforms for Methyl- and Dimethylaluminum Arrays.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b03448
Abstract: Trimethylaluminum finds widespread applications in chemical and materials synthesis, most prominently in its partially hydrolyzed form of methylalumoxane (MAO), which is used as a cocatalyst in the polymerization of olefins. This work investigates the sequential… read more here.
Keywords: platforms methyl; alme2; ligand platforms; alme2 alme2 ... See more keywords
Penta-coordinated or -valent: the nature of the chemical bond of some Ti-C-Al compounds.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00164d
Abstract: Detailed DFT calculations of the published [CpTi(μ2-Me)(μ2-NPPh3)(μ5-C)(μ2-AlMe2)2(AlMe2)(AlMe3)] 1 revealed the triple-bond nature of the Ti-C bond and thus being a methide carbon with 5 surrounding ligands. This finding was further corroborated by the derivates [CpTi(μ2-Me)(μ2-NPPh3)(μ4-C)(μ2-AlMe2)2(AlMe2)]… read more here.
Keywords: alme2; coordinated valent; cpti npph3; penta coordinated ... See more keywords