Alternating Heterochiral Supramolecular Copolymerization.
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DOI: 10.1021/jacs.1c00823
Abstract: In stacking-based supramolecular polymerization, chiral hydrogen bonding (H-bonding) monomers often prefer to adapt a homochiral monomer sequence. Herein, we investigated the polymerization of a chiral thiophene-fused cyclooctatetraene (COT) as a novel nonplanar-core monomer and found… read more here.
Keywords: polymerization; alternating heterochiral; cot; supramolecular copolymerization ... See more keywords