Aluminabenzene-Rh and -Ir Complexes: Synthesis, Structure, and Application toward Catalytic C-H Borylation.
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DOI: 10.1021/jacs.7b11127
Abstract: Aluminabenzene-rhodium and -iridium complexes were synthesized, in which the aluminum atom played as a proximal Lewis acidic site. Based on their structural analysis, aluminabenzene ligand could coordinate to Rh and Ir as a η5-pentadienyl ligand.… read more here.
Keywords: aluminabenzene complexes; borylation; complexes synthesis; aluminabenzene ... See more keywords