Aluminium complex as an efficient catalyst for the chemo-selective reduction of amides to amines.
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DOI: 10.1039/c9dt01806a
Abstract: We report an efficient protocol for the catalytic chemo-selective reduction of tert-amides with pinacolborane (HBpin) to afford the corresponding amines in high yields using aluminium complexes [κ2-{Ph2P(X)NC9H6N}Al(Me)2] [X = S (2a), Se (2b)] as pre-catalysts… read more here.
Keywords: aluminium; aluminium complex; chemo selective; selective reduction ... See more keywords
Aluminium complex-catalysed hydroboration of alkenes and alkynes
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DOI: 10.1039/c9nj01859j
Abstract: Catalytic hydroboration of terminal alkenes/alkynes with HBpin using the Al(III) catalyst, [κ2-{Ph2P(=Se)NCH2(C5H4N)}Al(CH3)2] (1), under mild and solvent-free conditions to afford corresponding alkyl/alkenyl boronate esters in high yield is reported. read more here.
Keywords: hydroboration alkenes; aluminium complex; alkenes alkynes; catalysed hydroboration ... See more keywords