Polymerization of ε-Caprolactone Using Bis(phenoxy)-amine Aluminum Complex: Deactivation by Lactide.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01364
Abstract: Polymerizations of biodegradable lactide and lactones have been the subjects of intense research during the past decade. They can be polymerized/copolymerized effectively by several catalyst systems. With bis(phenolate)-amine aluminum complex, we have shown for the… read more here.
Keywords: aluminum; polymerization caprolactone; aluminum complex; amine aluminum ... See more keywords
Controlled Synthesis of Dendrite-like Polyglycerols Using Aluminum Complex for Biomedical Applications
Sign Up to like & getrecommendations! Published in 2023 at "ACS Omega"
DOI: 10.1021/acsomega.2c06761
Abstract: This work describes a one-pot synthesis of dendrite-like hyperbranched polyglycerols (HPGs) via a ring-opening multibranching polymerization (ROMBP) process using a bis(5,7-dichloro-2-methyl-8-quinolinolato)methyl aluminum complex (1) as a catalyst and 1,1,1-tris(hydroxymethyl)propane/trimethylol propane (TMP) as an initiator. Single-crystal… read more here.
Keywords: synthesis dendrite; aluminum; biomedical applications; dendrite like ... See more keywords
Highly Selective Polymerization of Rac-Lactide Initiated by Salen Aluminum Complex Bearing an Adamantane Derivative
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2021.1918683
Abstract: Abstract Using adamantane-1,3-diamine and 3,5-di-tert-butylsalicylic aldehyde as raw materials, the generated salen aluminum complex was characterized by 1H, 13C NMR spectroscopy and elemental analysis. After isopropyl alcohol activation treatment, the complex has good activity (70.3-95.6%),… read more here.
Keywords: salen aluminum; rac lactide; highly selective; aluminum complex ... See more keywords