Selected boron, aluminum, and gallium trihalide and trihydride anions
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Physics"
DOI: 10.1016/j.chemphys.2016.05.008
Abstract: Abstract Ab initio methods with flexible orbital basis sets are used to examine the electron binding strengths of tri-fluorides, tri-chlorides, and tri-hydrides of B, Al, and Ga. The adiabatic electron affinities are found to increase… read more here.
Keywords: aluminum gallium; selected boron; binding strengths; electron ... See more keywords
Unravelling the Potential of Ylides in Stabilizing Low-Valent Group 13 Compounds: Theoretical Predictions of Stable, Five-Membered Group 13 (Aluminum and Gallium) Carbenoids Capable of Small-Molecule Activation.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01630
Abstract: Computational investigations provide evidence toward the remarkable ability of strongly electron-donating ylidic functionalities in stabilizing singlet group 13 carbenoids with promising ligand properties. All of the proposed carbenoids are found to be considerably nucleophilic and… read more here.
Keywords: small molecule; aluminum gallium; gallium carbenoids; group ... See more keywords
Self-Assembly of Aluminum- and Gallium-Based meso-Metallaporphyrins.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02347
Abstract: The molecular meso-metallaporphyrin has been obtained from the reaction of AlMe3 with the bulky 4,5-(Ph2(HO)C)2-1,2,3-triazole (1). The presence of Al-Me groups coordinated to the triazole rings creates three different stereoisomers that were identified by single-crystal… read more here.
Keywords: aluminum gallium; self assembly; meso; meso metallaporphyrin ... See more keywords
The unique β-diketiminate ligand in aluminum(i) and gallium(i) chemistry.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04763h
Abstract: Over the past few decades, β-diketiminate ligands have been widely used in coordination chemistry and are capable of stabilizing various metal complexes in multiple oxidation states. Recently, the chemistry of aluminum and gallium in their… read more here.
Keywords: aluminum gallium; chemistry; diketiminate ligand;
Synthesis and optical characterization of mixed nanostructured aluminum–gallium oxy-hydroxide
Sign Up to like & getrecommendations! Published in 2017 at "Materials Research Letters"
DOI: 10.1080/21663831.2016.1232317
Abstract: ABSTRACT Nanostructured oxy-hydroxide materials with varied compositions of aluminum and gallium were synthesized in an environmentally friendly way with water as the only solvent. The tunability of optical properties of these materials through concentration ranges… read more here.
Keywords: oxy hydroxide; gallium; aluminum gallium; emission wavelength ... See more keywords