Gradual Size Enlargement of Aluminum-Oxo Clusters and the Photochromic Properties.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03397
Abstract: Metallic clusters, assembled by functional motifs, possess the attribute of regulating the properties by changing inorganic and organic components. In this work, a series of aluminum-oxo clusters, [Al6O(dmp)4(Hdmp)2]·2iPrOH [Al6-1, H3dmp = 2,2-bis(hydroxymethyl)propionic acid], [Al6(H2thmmg)6]·2DMF·2H2O [Al6-2,… read more here.
Keywords: chemistry; size enlargement; acid; oxo clusters ... See more keywords
From an aluminum oxo cluster to an aluminum oxo cluster organic cage.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06524j
Abstract: Presented herein is an example of the conversion of an aluminum oxo cluster (AlOC) to an aluminum oxo cluster organic cage (AlOCOC). We successfully synthesized the first example of an aluminum cluster-based organic cage-Al12 tetrahedral… read more here.
Keywords: organic cage; cluster; oxo cluster; aluminum oxo ... See more keywords